Authors
EJD Klem, CW Gregory, GB Cunningham, S Hall, DS Temple, JS Lewis
Publication date
2012/4/23
Journal
Applied Physics Letters
Volume
100
Issue
17
Publisher
AIP Publishing
Description
Of interest for both photovoltaic and photodetector applications is the ability of colloidal quantum dot (CQD) devices to provide response further into the infrared than is typical for other solution-processable materials. Here, we present a simple heterojunction diode structure that utilizes the extended infrared absorption of PbS CQDs. We show that device performance benefits from a discontinuous exciton blocking layer which improves charge separation without limiting charge extraction. By enhancing charge carrier mobility in the CQD layer, we demonstrate a planar heterostructure device with a power conversion efficiency of 5.2% under 1 sun illumination.
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